[1] Author: Kyung Min Lee, Byeongseok Kim, Juwon Lee, Gihan Kwon, Kwangsuk Yoon, Hocheol Song, Kyung Hoon Min, Sang Eun Shim, Sungwon Hwang and Taejin Kim

[2] Journal: Catalysis Science and Technology (IF=6.17)

[3] DOI: https://doi.org/10.1039/d3cy01103h

[4] Abstract

NiOx/CeO2 catalysts have shown promising results in various catalytic reactions, including the NO reduction by CO. In this study, we investigated the effect of oxidation and reduction treatments on the NO reduction by CO over pretreated NiOx/CeO2 catalysts. A series of oxidized and reduced supported NiOx catalysts were synthesized in two steps: (1) the pretreatment of CeO2 supports at different temperatures (400, 500, and 700 °C) under oxidizing and reducing conditions and (2) the synthesis of NiOx/CeO2 catalysts by an incipient wetness impregnation method (IWI) with a fixed surface density of 5.3 Ni per nm2 under specific conditions (oxidation/reduction) applied during the CeO2 treatment. The prepared catalysts were characterized via BET, ICP/OES, Raman, XPS, and XRD to understand their physicochemical properties. The results showed that as the pretreatment temperature increased, the physicochemical properties of NiOx/CeO2 catalysts were changed: a decreased specific surface area (SSA), decreased oxygen vacancy/defect sites, and an increased crystallite size. The oxidized NiOx/CeO2 catalyst at a lower pretreatment temperature displayed a better catalytic activity, indicating that the physicochemical properties of the catalysts were key factors in enhancing the catalytic activity. To understand the intermediate species and reaction mechanism during the NO reduction by CO, an in situ DRIFTS study was performed and a possible reaction mechanism was also discussed.