Journal: Journal of Hazardous Materials

Authors: Gihoon Kwon, Dong-Wan Cho, Hailong Wang, Amit Bhatnagar, Hocheol Song

Abstract: 

In this work, polyvinyl chloride (PVC) and paper mill sludge (PMS) were co-pyrolyzed under two environments of N2 and CO2. The pyrolysis process was assessed by conducting thermogravimetric analysis (TGA) and monitoring the evolution of gaseous products. The resulting solid composites were characterized using XRD, XPS, BET, and Raman analyzers, and their ability to catalytically activate persulfate (S2O82−) was tested by conducting methyl orange (MO) degradation experiments. Co-pyrolysis of PVC and PMS at the same mass ratio (1:1) in CO2 resulted in the highest production of H2 and CO (0.36 mol % H2 at 480 °C & 1.53 mol % CO at 700 °C). The characterization results revealed that the composite consisted of Fe3O4, highly graphitic carbon, and mesoporous structure. In MO oxidation experiments, the co-pyrolyzed composite actively generated OHradical dot and SO4radical dot− by activating S2O82− to achieve complete removal of 5 mg L-1 of MO during 100 min at acidic-neutral pH condition. The composite was also able to complete 3 successive cycles of MO oxidation without deactivation. Consequently, the feasibility of achieving the simultaneous production of energy resources and catalyst via industrial wastes utilization in pyrolytic process was demonstrated. 

Keywords: Co-pyrolysis, Waste management, Catalyst, CO2 utilization, Azo dye degradation, Persulfate activation

DOI: https://doi.org/10.1016/j.jhazmat.2020.123173